Crystal structure of μ-(oxalato)-bis[(αquα)-(diethylenetriamine)nickel(ΙΙ)]diperchlorate monohydrate,C10H32CI2N6Ni2O15
نویسندگان
چکیده
منابع مشابه
Crystal structure of bis(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis[n-butyltrichloridostannate(IV)]
The Sn(IV) atom in the centrosymmetric anion of the title salt, (C4H7N2)2[Sn2(C4H9)2(C2O4)Cl6], is coordinated in a distorted octa-hedral mode by two O atoms of a bridging oxalate moiety, three Cl atoms and a C atom of an n-butyl group. The latter is disordered over two sets of sites in a 0.66:0.33 occupancy ratio. N-H⋯O and N-H⋯Cl hydrogen bonds involving the 2-methyl-imidazolium cation and ne...
متن کاملCrystal structure of μ-oxalato-κ2 O 1:O 2-bis[(dimethyl sulfoxide-κO)triphenyltin(IV)]
In the previously reported [C2O4(SnPh3)2] complex [Diop et al. (2003 ▸). Appl. Organomet. Chem.17, 881-882.], the SnIV atoms are able to formally complete their coordination by addition of dimethyl sulfoxide (DMSO) mol-ecules provided by the reaction medium, affording the title complex, [Sn2(C6H5)6(C2O4)(C2H6OS)2]. The SnIV atoms are then penta-coordinated, with a common trans trigonal-bipyrami...
متن کاملCrystal structure of catena-poly[[aquadi-n-propyltin(IV)]-μ-oxalato]
The title compound, [Sn(C3H7)2(H2O)(C2O4)] n , represents the first diorganotin(IV) oxalate hydrate to be structurally characterized. The tin(IV) atom of the one-dimensional coordination polymer is located on a twofold rotation axis and is coordinated by two chelating oxalate ligands with two slightly different Sn-O bond lengths of 2.290 (2) and 2.365 (2) Å, two symmetry-related n-propyl groups...
متن کاملCrystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]]
The structure of the title compound, {(NH4)2[Cu(C2O4)2]} n , at 100 K has monoclinic (P21/c) symmetry with the CuII atom on an inversion center. The compound has a polymeric structure due to long Cu⋯O inter-actions which create [Cu(C2O4)2] chains along the a axis. The structure also displays inter-molecular N-H⋯O hydrogen bonding, which links these chains into a three-dimensional network.
متن کاملCrystal structures of μ-oxalato-bis[azido(histamine)copper(II)] and μ-oxalato-bis[(dicyanamido)(histamine)copper(II)]
The title compounds, μ-oxalato-κ(4) O (1),O (2):O (1'),O (2')-bis-[[4-(2-amino-eth-yl)-1H-imid-azole-κ(2) N (3),N (4)](azido-κN (1))copper(II)], [Cu2(C2O4)(N3)2(C5H9N3)2], (I), and μ-ox-al-ato-κ(4) O (1),O (2):O (1'),O (2')-bis-[[4-(2-amino-eth-yl)-1H-imidazole-κ(2) N (3),N (4)](dicyanamido-κN (1))copper(II)], [Cu2(C2O4)(C2N3)2(C5H9N3)2], (II), are two oxalate-bridged dinuclear copper complexes...
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 1997
ISSN: 2197-4578,1433-7266
DOI: 10.1524/ncrs.1997.212.1.123